With the advance of the Internet and the emerging electronic information resources, chaos remains as a constant phenomenon on the Internet. The purpose of the article is to study the solutions through methodologies of knowledge organization from different domains, in order to achieve the efficiency of knowledge discovery. An analytical comparison is taken among the systems of classification & cataloguing, search engines, data mining, metadata, semantic network, and topic maps. The issues of origins, theories & methods, current status & trends are also reviewed. In the findings, authors suggest that relationship-centric should be highlighted as a key framework for knowledge organization theory. Besides, some factors related to scale, economics and dynamics should be taken into consideration to achieve knowledge discovery.