The principal objective of this study was to determine the sorption (S), diffusion (D) and permeability (P) coefficients of DMMP, bromobenzene, chlorobenzene and nitrobenzene for the nature rubber blends with chloroprene rubber (75 type of mask) and bromobutyl rubber (92 type of mask) in different anti-oxidants. The sorption experiments were performed at 25, 40, 50 and 60℃and these results are used to estimate the Arrhenius parameters. The results are discussed in the correlation of rubber with toxicant penetrant properties.