The purpose of this paper is to study the vocational assistance and employable power of the students graduated from scientific-technological university. The exploration method has been used. One of the methods is to build a conceptual framework linked with vocational assistance and employable power of the students. Another is to set up a website for vocational assistance that provides students with on-line counseling service and necessary assistance. The results reveal two main findings. First, the factors influencing employability are students' individual personality and career plan. At school, they need department curriculum program design, the implementation of teaching, and students' job career assistance plan; beyond the school campus, employers' requirements and evaluations, and social and economic conditions become critical. Second, it is necessary to build a vocational counseling website, in which it must include job-related personality test and sufficient information related to students' tights. With respect to how to enhance employable power, the learning lessons include work attitude, professional knowledge and skills, the ability of presentation and communication, etc. Through the vocational assistance platform, it combines students' personality, coupled with job market's demand conditions and the expectation of big market environment. It then can enhance individual knowledge, intention and skills. The real value of this study is that it is the first one establishing vocational assistance website, for which after experiencing one-month demonstration more than 500 people have searched. In addition, we also took part in the first-time innovation website competition, in which we obtained the second award with bonus and a paper of prize. It is apparent that more confidence has been strengthened to build and promote the website platform.