E-learning is flourishing in higher education due to its ability to lift time and place restrictions from teaching and learning. Because many library staff has not received professional education, more E-learning curricula and programs by Library and Information Science schools is something that many libraries in Taiwan look forward to. Facing demand for E-learning from library staff, the Graduate Institute of Library, Information and Archival Studies (LIAS) at National Cheng-Chi University undertook an experimental curriculum project. The purpose of this study was to develop an E-learning master’s program with six E-learning curricula for library staff and instructors in senior high schools in accordance with quality assurance mechanism .The study was conducted as action research with five stages as follows: (a) describing the problem and its focus; (b) exploring some action options for the problem; (c)seeking collaborative partners and discussing; (d)undertaking action options: the five lecturers of the LIAS planned and developed six E-learning courses with web-based learning systems; (f) evaluation and feedback: six courses were modified according to student learning outcome assessments and course reviews. In 2008, six E-learning courses were developed and program and curricular accreditation was applied for from the Ministry of Education. Six e-learning courses were Information, Organization and Access; Research Methodology; School Library Management; Seminar on Archival Studies; Seminar on Library and Information Science; and Digital Libraries. In addition to describing the planning and implementation of the curriculum, the article also reviews the effectiveness of E-learning teaching and learning, as well as offering final conclusions and recommendations.