The study namely aims at exploring the process of starting an enterprise for "E Thematic B&B" business operation at Kenting area. Meanwhile, it had been conducted by means of literature review and depth-interview methods, and analyzed through NVivo 8.0. Furthermore, the results are cited as follows: (1)Hopefully the owner would promote the appropriate and accurate sense of B&B to guests via conscientious standards and its operation even though the policies and regulations have not been settled by the government in Taiwan. (2)The owner would enhance the high-quality of B&B business operation in order to decrease the negative competing outcome for prices and be instead of overlapping alternatives. (3)It is expected to segment the differentiations among competitors of B&B enterprises through particular architecting, organic meal offerings, and interpretation of attraction spots surrounded the location. More interestingly, the words of mouth from re-purchase guests may be the critical marketing effects to the thematic B&B business operations. (4)Finally, the owner looks forward to appealing the guests who have consensus and ideology on issues for thematic B&B operations.