Purpose: This study is aimed to analyze the performance of each combined skill employed by LI Xiaoxia, the elite table tennis player, and to study the performance predictions resulted from using each skill. Method: The study target is LI Xiaoxia, the world's top three player. The study scope includes the games of the top four in 2010-2012, as well as the 7 games she attended in the Worldwide competition. The table tennis combined skill analysis chart is the study tool. Based on the observation method, the data collected are analyzed with descriptive statistics, stepwise multiple regression analysis. The research scope includes those games they attended. The research tool is the three-staged skill analysis chart and based on the observation method, the data collected are analyzed to authenticate the research assumption by three-stage skill analysis、stepwise multiple regression analysis, and independent t test. Results: 1. For LI Xiaoxia's performance status of using the compound skill, the scoring rate for the stage in receive attack phase is excellent, followed by serving the ball to attack, mutal attack phase. The usage rate for the mutal attack phase is the highest, followed by serving the ball to attack, receive attack phase. 2. The best method to predict LI Xiaoxia's performance is the scoring rate of receive attack phase. Conclusion: The elite female table tennis player Li Xiaoxia technical expertise receive attack phase.