Background: The library should provides a good reading space and a comfortable environment. Therefore, the environment of a library affects people’s learning efficiency and health. Purposes: Due to the unique climate in north Taiwan-Taipei, since we want to know how to maintain thermal comfort of the indoor environment. First, we have to understand the relationship between environmental data and reader's thermal comfort. Then, we can do research and analyze the data we measured. We also learn more about the difference between the green building and non-green buildings. Methods: Timing measurement to get the indoor and outdoor environmental data, meanwhile we send questionnaire of indoor environmental comfort. Then, Excel was used to organize the information. Finally, we analyze the cross-correlation coefficient by the statistical software, SPSS, to draw conclusions. Results: The data shows the relevance between library buildings and indoor comfort. The green buildings have some outstanding values in indoor environment. The researcher found that building facade materials, window-wall ratio and design affect indoor comfort. Conclusions/Implications for Practice: Cross analysis of different library buildings' data concluded the ratio of different types building. We compare the numerical value and do weighted arrangement to raise suggestions for solutions. We would like to make constructive suggestions that can improve the library building's thermal comfort to the relevant units.