This study, with a perspective of Corpus Linguistics, tries to utilize a CART analysis (Breiman et al., 1984) and a VARBRUL analysis (Rand and Sankoff, 1990; Robinson, Lawrence, and Tagliamonte, 2001; Sankoff, Tagliamonte, and Smith, 2005) with a large number of corpus data to prove that the grammar rules of the three structural particles "de" in Chinese are consonant with its real use by language users, and to prove that language users are aware of the structure before selecting an appropriate particle(徐陽春,2004). Moreover, the quantitative analyses show the lower degree of misuse between 「的」/「地」 or 「的」/「得」, but higher degree of misuse between 「得」/「地」. This study suggests that independent usage for each structural particle is required, since the quantitative analyses of corpus data show the consonance with the real use of language users. Additionally, three conceptualized models for the three structural particles have been proposed. This study expects to contribute to the composition of Chinese dictionary, Chinese language teaching, language policy, and natural language processing.