The aim of this study was to explore the effects of self-efficacy and social network on entrepreneurial passion and entrepreneurial intention for the entrepreneurs. For the recent years, entrepreneurial activities have been prevailed, and thus the factors affecting entrepreneurial behaviors are appealed great concerns. It is deserved to be concerned that entrepreneur’s self-efficacy and social network are the important factors affecting entrepreneurial intention, since they may influence the subsequent entrepreneurial behaviors, strategy positioning, as well as managerial performance. The current study performed an empirical analysis, where the participants who were the executives in the small and medium-sized enterprises were selected. A web questionnaire survey was conducted and totally 521 samples were collected. Subsequently, the proposed hypotheses were verified by using hierarchical regression analysis method. The results revealed that there were significantly positive effects of entrepreneur’s self-efficacy and social network on both entrepreneurial passion and entrepreneurial intention. Besides, the mediating effect of entrepreneurial passion was justified. Based on the results, we discussed the implications of finding, and then proposed some referencing suggestions for enhancing people and/or related units entrepreneurial intentions.