The paper is to study the effect of section scale factor for coating steel structure fireproof capacity. Using different H shape steel beams of section scale factor in test, and painted around M1, M2 two frieproof coating materials, after water evaporable of specimen to counterweight and proceed fire resisting test. Using the building fire standard rising temperature curve under CNS 12514 to be heated condition, and study the relationship of section scale factor, coating thickness and fireproof duration. The test result detect: In the same covering material and thickness, the steel beam fireproof duration will lengthen caused by section scale factor under A scale fireproof test; the relationship between t/T of freproof duration with covering thickness and section scale factor will regression change to two parallel by differ covering thickness. The slope of line and its intercept will changed by differ covering material.