This paper attempts to formulate a freight routing model for time definite carriers. The optimization model takes the characteristics of the freight routing problem time definite carriers facing as well as their internal operation networks into account and treats that as a multicommodity network flow problem. Furthermore, we propose an algorithm for solving it based on a column generation scheme, e.g., Dantzig-Wolfe Decomposition Algorithm. The freight routing model has been tested on a certain major carrier's network in Taiwan. The results show promising. Additionally, in order to make carrier's staff easily use the system and diagnose the data integrity, the model is constructed under a decision support system developed by a Geographic Information System tool, MapInfo. The system can quickly display the operation network as well as process queries for the results determined by the optimization model.