Combating climate change required social economic development huge changes. Since the reform and opening-up policy,the economic structure of China has obtained certain changes; however,comparing with some developed countries,it still has further optimization space. Based on the input-output table of 1992,1997,2002,2007 and 2010,using the IO-SDA( Input-Output Structure Decomposition Analysis) method,this article decomposes the change of carbon emissions into energy structural effect,energy intensity effect,value added effect,Leontief inverse matrix effect and final demand effect,therefore developing the effect of the economic structure changes to the CO2 emission. The results show that China’s increasing emission caused by energy consumption is mainly due to the final demand effect and the Leontief reverse matrix effect. It also shows that except for 2002- 2007,the energy intensity effect is always negative and is the main reason of the CO2 emission reduction. So it can be concluded that final energy mix has only been optimized during 1997- 2002,and in the other years,it ’s moving toward to higher carbonation. By constructing the influence coefficient and the reaction coefficient of carbon emission,and making relevant assessment,the results show that the basic industries of the national economy are energy intensive,the future energy conservation should focus on the reduction of the proportion of the secondary industry in the national economy,which is based on differentiated policy of different industries. For example,mining and washing of coal sector should keep certain share and couldn’t decrease all the time,more technology innovation energy saving policy should be paid attention. Manufacture of general purpose machinery sector could consider the energy saving by improving the energy efficiency. Manufacture of non-metal mineral products sector could decrease its share as far as possible to ensure primay requirements from production and consumption. Manufacture of food and process of tobacco sector and real estate developmeng,public management,social security and social organizations could increase the share in the total economy.