Facing mortality is human’s common problem so far. Longing not to die rises Immortal’s thought. Fidning the way of becoming Immotals and pursuiting a long life are Taoism’s fundamental theories. Bai-Yu-Chan was the Fifth Master of Taoist Inner-alchemy school in Southern Song Dyns. His origiional name is Ge-Chang-Geng whose family had long since livied in Min province. Inscribing his grandfather who had been the head of Qiong province, he named himself Hai-Qiong-Zi which means mister who came from Qiong place by the sea as a secondary personal name. After his father was dead and mother gave in marrage again, he changed his name to Bai-Yu-Chan and became Chen-Nan’s student. He learned everything about Taoism of Chen-Nan. At the Jia-Ding era, government recruited him to capital and settle him at Tai-Yi temple. He was sainted as “true men” and named Zi-Qing-Ming Dao (紫清明道)which means he is the top in the Taoist. There are two reasons why I want to discuss Bai-Yu-Chan’s verse. First, statistics show that the word- Xian has the highest show rate in Tang-Song dynasty’s poetry. Second, Bai-Yu-Chan was an important figure at Inner-alchemy school and his poetry abound with Xian’s savor. He wrote 137 poem that can be divided by two topics. One is Yao-Xizn (遊仙) –a state which people’s soul could travel freely with no obstacle. Another is Xiu-Lian (修煉)which is a method that human could follow it to make a perfect virtue. People wrote Yao-Xian verse through the expeirnce of dream generally. Different from that, Bai-Yu-Chan based on Cun-xiang-si-shen(存想思神)which is a kind of Taoism practice. By way of this, his soul could experience traveling in the empyrean which makes his poetries of Yao-Xian have a special feature. According to the Xiu-Lian’s idea, the function of human body is similar to a tripod which cold extract the real inner alchemy from. Inside human body, essence(精), energy(氣)and spirit(神)are gift medicines. Human can guide them to circle in body by will. Beside those, Bai-Yu-Chan thought a mind which could match the Way is the true elixir of life. Xian is a person who find the Way, beyond body, honor and interest and live naturally without feeling of vexation. In conclusion, we may find Xian’s cloud Taoist nostalgia for Xian’s homeland hang over the horizon of Bai-Yu-Chan’s verse. Human life is evanescent, having a happy reunion is so hard, separation is common. Those are the pathos of Bai-Yu-Chan’s poetry.