This paper explores the architecture, which new XML technology to design the new electronicdocument delivery system combine with the existing library system, assist the user to query by libraryOPAC and retrieve information entity rapidly in Web. In order that, not only accelerate thedevelopment for electronic publishing, but also position the library role of information mediationbetween user and provider, archive information circulation and provide secure copyright-fee throughthe efficient electronic document delivery and payment mechanism. The proposed electronic documentdelivery system have three contribution: (1) resolve the electronic document payment, (2) shorten thetime retrieval between enquiry and electronic document entity, and promote the recall-rate of enquiry,(3) position the library as a medium between information and user in web, with reducing the load ofcollection.