Free will, a traditional problem with the western philosophy of mind, has attracted close attention and has been highly valued, and Thomas Aquinas, as the authority of medieval scholasticism, was one of the founders of the western study of free will. He descriptively explained the freedom of will, meticulously analyzed its concepts, and introduced a series of categories in his discussion of free will, like emotional intention and rational intention, inevitability and contingency, human behavior and humane behavior. Aquinas’s theory was criticized and censured afterwards. But by reconciling determinism and non-determinism through the use of aforementioned categories, he not only gave us a new way of thinking to solve the traditional problem of free will, but also provided us with a new paradigm to understand the prospect of human behavior.