Traditionally, Taiwan businesses for most categories of industry were manufacturing and exporting companies, mainly relied on production skills and cost advantage to acquire international export market. But, in the recent decades, because of higher operating cost in Taiwan, and lack of ability to build-up market position in foreign. These traditional exporting companies had faced serious depression. This acticle studied a representative case of shoes production and exporting company, who had joined-in a global manufacturing and marketing collaborative network, with an idea of customer relationship serving concept. Along with the growth of supplier's or purchaser's business network, the collaborative to member's needs for collaboration value, and their supporting capabilities to value network also changed. This study discover that more the input are specialized in the collaborative relationship, more possible the supplier could strengthen their capabilities to serve purchaser by continuing learning from collaborator, also own the differentiated value to purchaser More than that the case company had grown to a international company with the transforming of collaborative value net. It means that a company even in matured industry, who hopes to hold nonsubsitutable manufacturing capabilities, specialization and enlarge supplying scale are feasible ways.