The performance of decolorization in the effluent of methylene blue and methyl orange using □-resin catalyst process were studied. The dominant factors of catalytic oxidation were investigated for the decolorization of sample dyes. It was found that an overall 99% color removal can be achieved for methylene blue in 70 minutesand methyl orange wastewater in 30 minutes reaction. The ADMI of methyl orange effluent can be decreased from 47560 to 205 and the ADMI of methylene blue effluent can be decreased from 84030 to 224 at suitable conditions. The results indicated that the reaction condition strongly influenced the efficiency of color removal. However, the pH value、reaction temperature、oxidant concentration、pollutant concentration significantly affected the decolorization of dye wastewater in□-resin catalyst process.