There are four means in oil analysis including routine performance analysis, spectrometric analysis, ferrographic analysis and grain analysis in order to control and valuate the estate of used oil and equipments. We can analyze the reason of invalidation of equipments. First, we must pick-up and establish timely, accurately and largely character information from the oil used in these equipments. Second, we must put these character information into knowledge based and establish relevant mathematics model. This paper discusses and solves these problems in basic spectrometric analysis about how to put these character information into knowledge base and establish relevant mathematics model.