Option is one type of nonlinear financial derivatives with highly sensitivity to volatility. This article also converse how agents calculate TXO by using different volatilities and hedge ratios without pursuing the circumstance of hedge and compare the differences of VaR between in-the-money and out-of-the money. The empirical evidence indicates that using GARCH volatility to obtain VaR for option is far smaller than using historical volatility, implied volatility and ANN volatility. It is also more stable For the risk of measuring integrated option, the performance indexes of VaR model illustrate that the VaR of GARCH volatility is far better than historical volatility, implied volatility and ANN volatility. Furthermore, empirical results also show that the performance of Gamma-rule VaR is better than Delta rule VaR.