The transnational crime has widely spread in the European Union (EU) with the previous EU enlargements and under the impact of globalization. In addition, the establishment of the European Single Market had successfully achieved the four free movements such as goods, persons, services, and capitals. After the four free flows and under the arrangement of Maastricht Treaty, it also enlarged the formation of European criminal markets and caused a serious deterioration in Social stability, by far which are really threatened the whole interests of EU Member States. Therefore, the issue of internal security in the EU has become Europe-wide problem, which can not be solved by any one of Member States separately and they could not prevent these complex issues alone, too. Therefore, it is necessary for the EU Member States to enhance EU transnational police-cooperation and to effectively protect EU internal security. Furthermore, to push the Member States eager to take joint control of the international cooperation. Police cooperation is the most important part of Justice and Home Affairs in EU, it is also the inevitable result of EU political and economic integration. EU police cooperation is reflected mainly in the European Union and its co-operation between Member States. This study attempts to take “the liberal intergovernmentalism" approach, to deeply analyze the positions of EU, Member States and its related agencies and how to develop the EU police cooperation from the historical process of European integration. Finally, this study will assess its achievements and limitations and submit to the conclusions and recommendations as a valuable reference for Taiwan.