RFID technology is nowadays gradually widely applied to books location detection and searching, and to gather statistics of book accessing and reading rate. In comparison of barcodes, RFID tags not only replace the function of barcodes, but also hold information relating to book location, last borrow date, author, and title etc. Although the RFID provides the convenience and enhances the function of tracking, doubts that it may infringe on readers' privacy also arise. This article is aimed on the analysis of privacy protection issues arise from the application of RFID in libraries. First, the characteristic of RFID, the relationship between RFID and library management, and the current status of RFID in libraries will be introduced. Then, the function of RFID and the privacy protection concerns will be discussed. Finally, the suggestions about regulation aspect will be provided as conclusion.