Lianmianzi means a single inseparable word that is composed of two syllables, including disyllabic roots with two words of same initial, the same final, or the same initial and final. Lianmianzi is generally thought to be a combination of syllables instead of meanings. According to the process and constitution, ancient Chinese mostly consists of one-syllable words. Two-syllable words and multi--syllable words only occupy a small part in ancient Chinese. As a matter of fact, most multi-syllable words are two one-syllable words applied consecutively. Because of the same forms with two-syllable words, they are misunderstood to be of two syllables.Generally speaking, Lianmianzi is supposed to be with three characters. Lianmianzi consists of only one morpheme, and disyllables with phonetic relationship, and loose written forms. However, there are still different opinions on the phonetic relationship between the disyllables. Consequently, with Shijing( the book of poetry) as examples, the essay tries to research to the Lianmianzi without phonetic relationship. Then, the theory that ther is no phonetic relationship between Lianmianzi still has some room for discussion.