Sun Chuan’s “Pacifying Liaotung” (Liaotung: toponym) is not only simply seeking an alliance between Wu and Liao, but also relating to national strategy of the policy of “Allying Shu to against Wei” determined by Sun Chuan, the purpose of which is to increase more assistance for alliance to fight against Wei. Therefore, it will be insufficient to explain why Sun was so insistent to advance this matter, and to specify the cause of his failure by the historical fact that Sun’s diplomatic inexpediency is the cause of his failure, or his benighted and unmoral behaviors reveals in the late stage of his reign. This article, thus, intends to cut in from angles of the strategic status of Wu, Wei,and Shu (three small nations), the material requirement of Wu’s horse issue,the unified vision of Sun’s personal volition, and the development of navigating career, so as to provide a comprehensive and deep realization about this event.