The Bureau of Energy of MOEA promotes relevant technology research and development of low carbon energy, among them the carbon capture and storage (CCS) is a very key technology. The energy fund supports development of the calcium looping technology for capturing CO2 in a 1.9 MWt pilot plant. The distinguished feature is the combination of post-combustion capture technology using carbonation process and oxyfuel combustion calciner for sorbent regeneration, with the abundant limestone (CaCO3) serves as raw materials. At first the limestone calcinate into lime (CaO) as the adsorbent, it has high absorption capacity and can capture more than 90% carbon dioxide. When the adsorbents lose activity and can be used as raw materials for cement production and flue gas desulfurization. The calcium looping process makes the adsorbent free and produces no materials that have extensive development potentiality in the future.