The current trend in volleyball is mainly based on high spike touches combined with fast and changeable multi-level play. The psychological quality of the players on the field directly affects the key to the team's victory and defeat and indirectly affects the team's overall morale. The setter is the soul of the volleyball game, and his hands transform over 80% of the ball into an attack. Therefore, teammates and coaches will highly expect the excellent performance of the setter during the game, and it will also generate tremendous psychological pressure. The researcher in this study has many years of experience as a national team setter and is currently a teacher and leading volleyball coach in the universities; he knows that the important role setters play in the game has a significant impact. Therefore, this article discusses the psychological factors of volleyball setters' on-the-spot performance and puts forward solutions, hoping to improve the on-the-spot performance of Taiwan volleyball setters.