This research discusses the impacts of anti-corrosive methods for the surface of steel structure on the adhesion and fire-resistance capability of coating materials. After the sand-blasting process on the surface of steels, three anti-corrosive paints, inorganic znic richprimer, oxygen znic richprimer and red lead, were chosen to be the conditions of anti-corrosive process and unpaint in order to investigate the difference between use of anti-corrosive process or not. The results show that the specimen using red lead has less adhesion with coating materials and will reduce the fire-resistance capability. But the specimen with blasting sand and no paint, on the other hand, will give higher adhesion between coating material and steel because of the rougher specimen surface caused by corrosion and as a result will guarantee the fire resistive rating of coating materials.