The combination of passive sample and thermal desorption technique provides advantages such as light weight, small size, no power requirement went, low detection limit, no solvent interference and without pretreatment, etc. over conventional sorbent-desorption technique. Toluene was used as the test reagent to evaluate a passive sampling and thermal desorption method. ATD stainless stell tubes packed with Tenax-TA tube is about 1.85 ± 0.13 ng/ppm/min, and it is 2.18 ± 0.06 ng/ppm/min for Carbopack B tube. Surface velocity among 0.10 m/s to 0.41 m/s does not influence uptake rate. Sampling direction has no influence on uptake rate. The uptake rate increases with increasing temperature, but it is not consistent with thermal theory. After four hours ssampling, the uptake rate of Tenax-TA tube decreased, however it remains constant for Carbopack B tube. No reverse diffusion was observed. ATD passive sampling tubes with thermal desorption and active sampling charcoal tubes with wolvent desorption were compared in the field. Although statistical bias exists betwen them, the data from these three sampling tubes are consistent.