The atmospheric turbidity is one very important factor in the air pollution measurements and monitoring with remotely sensed data, especially in visible bands. The scattering effects of atmospheric molecular and aerosols in varying atmospheric turbidity conditions can influent the original spectral information of remotely sensed data strongly. From another point of view, the atmospheric turbidity can be estimated by evaluating the information variation induced by the scattering effects. Tanre, et al., proposed the Structure Function (SF) to estimate the atmospheric optical depth in 1988. Their study result showed that the Aerosol Optical Depth (AOD) can be assessed with Landsat TM data by assuming the landcovers are same in the set of multi- temporal TM images. In this study, the SF method is improved for applying in Taiwan area because of the rather rough terrain and complex landuse properties. Besides, the higher spatial resolution SPOT data and hourly GMS- 5 data were used to derive the AOD. The result shows the improvements in this study can get satisfying result, and it reveals we can derive these satellite data for the monitoring of hourly air pollution and air quality variation.