There is little literature on a comparative study of vowel frequencies in the lexicons of English and Chinese. We discuss some theoretical issues involved, such as the choice of IPA symbols, how to determine unstressed syllables, and whether a diphthong should count as two vowels. We then discuss different ways of calculating vowel frequencies. Our results show that, in both English and Chinese, pre-nuclear glides occur at fairly low rates, with little effect on vowel frequencies. The most frequent vowel in English is [?], apparently because English has many polysyllabic words, most of which have an unstressed syllable, whose vowel is usually [?]. If we exclude unstressed syllables, then in both English and Chinese, the total frequency of high vowels is similar to that of non-high vowels. Among English high vowels, front vowels occur more frequently than back vowels and tense vowels occur more frequently than lax vowels.