Volleyball is an extremely competitive game and players are required to have high levels of physical performance and techniques during the game. The techniques of serve, re-serve, setter, smash and defense are high intensity movements that are low proportion of the total number of actions during the game. On the other hand, preparing positions, moving steps and jumping are low intensity movements that are high proportion of the total number of actions during the game. According to analysis of attacking and defensing time, energy from ATP-PC system is most commonly used. Only a little energy from Glycolysis system leads low blood lacic acid and heartbeat during the game. Energy rich phosphate compounds are burned to provide energy for muscles in anaerobic metabolism during the volleyball game. However, with the extension of attacking and defensing, Glycolysis system has to step in to provide more energy, and re-sets the ATP during recovery period. The purpose of this study is to promote volleyball players’ performance by analyzing their blood lactic acid, heartbeat, and intensity of the game and providing appropriate training based on energy metabolism system.