The main purposes of this research were to investigate the influence of athletes' technological creativity, coach leadership style and athletes' performance. This sampling object of research were 15 basketball teams in middle of Taiwan, with 379 usable questionnaires and returned rate is 75.80%. The research method included technological creativity scale, coach leadership style scale and performance scale. The statistical methods, such as Descriptive statistics, Confirmatory factor analysis (CFA) and Structural equation model (SEM), were used to perform analyses. The main findings of this research were: 1) athletes' technological creativity would significantly positively influence performance. 2) athletes' technological creativity would significantly positively influence coach leadership style. 3) coach leadership style would significantly positively athletes' performance. 4) athletes' technological creativity had mediating Effect to influence performance by the coach leadership style. The result showed that athletes' technological creativity and the coach leadership style would positively influence on athletes' performance, and the athletes' technological creativity would upgrade performance by different coach leadership styles. The research suggested that athletes would stimulate technological creativity and look for suitable coach leadership style to promotion performance of competition and to achieve the purpose of fostering high quality athletes.