Assessment of CO_2 emissions is the foremost imperative evaluation tool in modern green buildings and carbon footprints. The key to its success is dependent upon a reliable database system of CO_2 emissions along with an accurate and simple application. This research has been instituted based on more than 300 databases collected from CO_2-emitting air-conditioning units and 22 applications of estimated CO_2 emissions during graduate school. 42 actual air-conditioning system projects are then individually analyzed to derive emitted CO_2. Accuracy of the estimate is backed by coefficient of determination, R2, averaging above 0.9 using volume or capacity of the air-conditioning to formulate CO_2 emissions. It offers a simple assessment method for estimating reliable CO_2 emissions in the design stage by evaluating the impact the construction industry has on the global environment. Sustainable design and assessment of carbon footprint hence has made a significant contribution to green building.