This paper investigated the relationship between corporate governance and capital structure about construction industry which is publicly traded in China and in Taiwan during the period from 2003 to 2013. The leverage represented the capital structure as the dependent variable. Board size, size of the firm, CEO/Chair duality, ownership concentration, the number of board meeting and shareholding of directors represented as corporate governance as the independent variables. Empirical research covered descriptive statistics, Pearson correlation and multiple regression analysis. The results showed that leverage has positive effect on board size, size of firm, the number of board meeting and shareholding of directors, while it has negative effect on CEO/Chair duality and ownership concentration in Taiwan. The results showed that the relationship between corporate governance and capital structure in Taiwan re consistent with the previous literature, while corporate governance and capital structure are different in China.