Volleyball activity, according to the metabolic system of energy inside human body, is one of anaerobic sporting events. At the initial state of action, respiration rate in the cellular mitochondria increases dramatically. Ten-fold amount of oxygen is required for oxidative phosphorylation to generate enough quantity of ATP to meet the energy demand for human body. During this process, more free radicals are also produced. Free radicals would induce the structural change of human DNA. Publications of clinical studies have confirmed that large amount of free radicals be the original causes of severe chronic diseases including cancer, atherosclerosis, diabetes, aging and Parkinson’s disease. Therefore, athletes, undergoing highly-competitively training exercise and top-level completion, have to pay attention to adjust the training intensity according to their own physical state and take antioxidants as a supplement to prevent any oxidant injure occurred.