The nanometer technology is the main issues in 21 century. According to the literature review, it appears that the nanometer technology will be in charge product design in the future. Most of product will relate to nanometer technology and improve the environment protection by applying it. At the same time, nanometer is considered as an extremely good material of environmental protection. In the future, product design and development will be closely lined with nanometer, especially for the people of engaging green product design and development. Therefore, the main purpose of their study is to reorganize and understand the development system of materials of nanometer technology. Furthermore, the case study accomplishes structure of green products in terms of material application of nanometer technology by using green design checklist, MET matrix analysis and LiDS Wheel. As a result, the study provides the important reference and standard of green product design from materials of nanometer technology for designers. Then, materials of nanometer technology can extend its application to new fields of environmental protection.