This study examines the relationships among the competence, hierarchical- characteristics similarity, nominal-characteristics similarity toward perceived supervisor support (PSS), and PSS toward turnover intention. Besides, the mediating effect of PSS is also explored in this study. The military members were selected as target sample. In the 399 pair of effective responses, we found five results: (1)The more an organizational member had competence, the more he/she would perceived PSS. (2) An organization member was similar to his/her supervisor in nominal-characteristics similarity; he/she would perceive more PSS. (3)The more an organizational member perceived PSS, the lower he/she would perceive turnover intention. (4)The perceptions of PSS had a complete mediating effect on the relationship between perceived competence and turnover intention. (5)The perceptions of PSS had a complete mediating effect on the relationship between perceived nominal-characteristics similarity and turnover intention. In the end, this study discussed research findings both in terms of theoretical development and of practical management implications.