Banks have changed management comprehensive financial business of liberalization, globalization and large-scale for a long time. An important application of Technique for order preference by similarity to ideal solution (TOPSIS) is to evaluate the performance. Recently, researchers have suggested many ways to construct the decision matrix, the objective weight, and the method of computing the separation measure in the TOPSIS technique. The purpose of this paper is to propose the best combination of the decision matrix, objective weight, and measure of separation measure by simulation. A case study about the performance of the banks in Taiwan will be conducted using the proposed method.