Purpose: On the basis of the self-determination theory and theory of planned behavior, this study explored the factors influencing participant's behavior in extreme bicycle challenges as well as the relationships between these factors. Methods: Participants who engaged in extreme bicycle challenges and covered a minimum distance of 200 km per day were recruited. A questionnaire that focused on basic psychological needs, the theory of planned behavior, and cycling behavior was employed as the research instrument. In total, 463 valid samples were retrieved, and a path analysis of the collected data was conducted to assess the fit and effect of the research model. Data analysis was performed using the IBM SPSS Amos 22.0 statistical software, with the significance level set at .05. Results: The measurement analysis model exhibited a favorable overall fit with the actual data. The basic psychological needs of participants in extreme bicycle challenges had significant and positive effects on their attitude, subjective norms, and perceived behavioral control. Basic psychological needs, attitude, and perceived behavioral control had significant and positive effects on intention. In addition, perceived behavioral control and intention had significant and positive effects on behavior. Finally, attitude and perceived behavioral control mediated the relationship between basic psychological needs and intention. Conclusion: Meeting the basic psychological needs of extreme cycling athletes may enhance their intention to participate. A positive and proactive attitude, perceived behavioral control, and higher levels of internal and external resource control can promote behavioral involvement. Therefore, we recommend training strategies that enhance the physical, psychological, and skill-related dimensions of athletes; the establishment of a friendly and high-quality training environment; and the use of facilities that help athletes to strengthen their control over their internal and external resources.