This paper aims to take a serious study on related Metadata standards and issues of the digital museum projects by deploying three research methodologies: literature review, comparative study, and case study. This paper is composed by four parts as follows: related terminologies and coverage, typology of current Metadata development, research finding based on a comparison of four standards, and a case study of the Digital Archives Project in Taiwan. This paper raises three findings: (1) A variety of Metadata standards are developed for different purposes, and complementary to each other; (2) In order to achieve functionality optimization of Metadata, related standards are designed as dependent mechanisms, like union list, thesaurus, data model; (3) In terms of comprehensiveness and structure, disparity exists amongst a wide of Metadata standards. In practice this substantial customized phenomenon is reasonable for implementation of each digital museum project. This paper also presents four findings for a case study as follows: (1) challenging issues of Metadata implementation in digital museum project: (2) constructing a Metadata lifecycle model, (3) developing content analysis methodology; (4) building up the Metadata interoperability levels. Finally, this paper addresses four issues and suggestions as conclusion: adoption of Metadata standards, characteristics, facets, levels, quality assurance, and relationships of Metadata.