Students under cooperation education tend to be antipathetic, have a sense of inferiority, look down on themselves, and low self-concept under the pressure of educational elitism. Students under cooperation education in Department of Hotel and Restaurant Management at vocational schools are having trouble getting along with people, accommodating themselves to living and working condition; therefore, student's quest for self-concept and social adjustment is an important issue of practical management. Today, research considering cooperation education student's quest for self-concept and social adjustment is lacked, so such an issue deserve more attention in practical management and theory. Therefore, the purpose of the research focuses on understanding the relationship between their self-concept and social adjustment of Cooperative Education Students at Vocational School. The sample included 202 Cooperative Education Students and questionnaires were mailed as the instrument of data collection. Conclusions are as follows: cooperation education students' self-concept is normal. (M=3.23); cooperation education students' "social adjustment" is normal. (M=3.01); There is no significant difference among students' overall self-concept in different grade, but the significant difference lies in their self-concept in terms of professional knowledge, appearance, relationships with the opposite sex and teachers. significant difference lies in gender, overall self-concept, professional knowledge, appearance, and the relationship with the opposite sex; Cooperation education students' self-concept and social adjustment are closely correlated; The predictability of cooperation education students' self-concept for social adjustment reaches a high of 31%.