The purpose of this study was to explore the relationship between the role behavior and work effectiveness of military instructors, as well as the degree of identification and the evaluation to these factors from teachers’ points of view. The studied subjects were the teachers working in 26 public and private high schools and vocational schools at Tauyuan County. Totally 790 copies of the questionnaire were distributed, and 616 valid copies collected. The ratio of valid responded questionnaires was 79.5%. The actual data collected were analyzed by descriptive statistics, t-test, one-way ANOVA, Product-moment correlation, and the multiple stepwise regression analysis. The findings and results of this study were as follow: 1) Among the role behavior of military instructors, “service of security” got the highest identification, while “work ability” and “work performance” got the highest scores in work effectiveness. 2) There were significant differences in views of the role behavior and work effectiveness of military instructors according to teachers’ background variables, especially in “age”, “position” and “the quantity of class in a school”. 3) After eliminating the influence of personal background factors of those interviewed teachers, there was significant correlation between the role behavior and work effectiveness of military instructors. 4) On the prediction of worked effectiveness through role behavior, using “life guidance” to predict “work attitude,” “work ability, “ “work achievements” and overall “work effectiveness” had the best predictability, and degree of identification in “service of security” the teachers held with military instructors had an effective predictability to the work effectiveness of military instructors. 5) Teachers held positive attitude toward military instructors on “service of security,” “students affairs,” “work ability” and “work performance”; especially those whose job had direct connection with “students affairs.” 6) On the prediction of work effectiveness, “life guidance” was the most important factor, followed by “campus security” and “National Defense Course.”