Many companies use philanthropic performance as a means to build public relationship but care little about the environment. Environmental education thus needs to alert consumers to companies' environmental performance and urge consumers to take actions accordingly. This study explored how a company's environmental performance and philanthropic performance would affect college students' intention to buy its products. We ran an experiment with a convenience sample of 200 college students. The experiment introduced a fictitious shoe-making company and described its environmental and philanthropic performance to the students. Both performance could be either good or bad, and there were 50 students in each of the 4 performance combinations. The results suggest that college students prefer to buy goods from a company of good environmental performance than from a company of bad environmental performance. However, our findings also suggest that students—no matter they are concerned about the environment or not—are willing to buy from a company that has good philanthropic performance, regardless of its environmental performance. Implications of these findings for environmental education were discussed.