International institutes, such as Local Governments for Sustainability (ICLEI) and C40 Climate Change Leadership Group (C40), agree that the priority for mitigating GHGs emissions in urban areas is to inventory urban CO₂emissions, and suggest that the inventory should be done based on "2006 IPCC Guidelines for National Greenhouse Gas Inventories." Currently, the Taiwan Bureau of Energy of Ministry of Economic Affairs follows the Guidelines to calculate national CO₂emissions every year, as reported in the "Statistical Analysis of Taiwan Fuel Combustion Carbon Dioxide Emissions". On the other hand, the Environmental Protection Administration of Executive Yuan proposes "Guidelines for City Level Greenhouse Gas Inventories" following "International Local Government Greenhouse Gas Emissions Analysis Protocol." However, the calculations of the two levels of CO₂emissions (i.e., national and city) are based on different classifications of sectors and data sources. Additionally, urban CO₂emissions are insufficient for analyzing the relationship between land use change and spatial distribution of CO₂emissions. Accordingly, this study develops a quantitative approach for downscaling analysis on urban CO₂emissions. Using the Taipei metropolitan area and Kaohsiung City as case studies, the CO₂emissions on the city and district levels are estimated and, the temporal-spatial CO₂emissions patterns are illustrated.