Urban heat island has raised several key issues in Taipei metropolitan area. This study investigated how urban heat island affect the thermal environment by applying mobile transit measuring method at noon, evening and midnight on July 4th, 11th and 13th 2012 to collect the temperature data and contour of the research area. The analytical results show that the highest temperature area located at places with heavy traffic condition, high population intensity, and high building intensity. Meanwhile, temperatures were lowest in low population intensity area, green space, or mountain region. The hot area scattered in Taipei metropolitan area during daytime. The highest heat island intensity was 6.87°C at noon (12:00~14:00). After sunset, the high temperature area shifted to city center where anthropogenic heat is very high. The highest heat island intensity was 5.77°C at night (19:00~21:00) because human activity dominates and plays a significant role on heat island effect. At midnight, the city center is still be warm due to the high building intensity blocking the release of heat. Meanwhile, wind around the basin area causes rural areas to cool down faster than the center of the basin. Therefore, the highest heat island was 4.38°C at midnight. Moreover, comparisons of the 2012 study and 1999 study showed that the heat island pattern of Taipei metropolitan area differs. The heat island intensity of Taipei metropolitan area in 2012 was slightly higher than the study in 1999 at noon and in evening, but was almost identical with the literature data at midnight. Further quantitative analyses of relationships between heat island effect and some relative factors showed that heat island intensity had a positive correlation with population density and building cover ratio but had a negative correlation with green cover ratio. Based on these data, the following strategies are recommended for mitigating the heat island effect: (1) Decreasing anthropogenic heat of car, air condition or human activities; (2) maximizing green space; (3) improving paving materials as low heat parameters such as green wall, green roof or cool roof; (4) improving wind ventilation path in urban areas for releasing the heat in summer.