In this study, theory of planned behavior was used as main theoretical model and joined three important research variables (perception, response efficacy and action) according to the literature review to shape the study construction. The main purpose of this study was to understand elementary school teacher's environmental risk teaching behavior patterns and the relations of the mutual influence in the main behavior concepts. Stratified random sampling was used in this study. 539 elementary school teachers in central Taiwan were sampled to carry on the questionnaires, and finally 327 effective questionnaires were obtained and analyzed. SPSS 12.0 and LISREL 8.70 statistics software were uesd to carried on the statistical analysis. The important research results presented as follows: The overall elementary school teacher's environment risk teaching behavior model was fair fit the data (GFI=0.93, SRMR=0.039, RMSEA=0.057, CFI=0.98). Perception, subject norm and self efficiency positively and significantly influenced behavior intention. Perception and self efficiency positively and significantly influenced behavior. Behavior intention positively and significantly influenced behavior and action. The behavior intention explanation strength in this study reached to 52﹪, 63﹪ for the behavior explanation strength, and 29﹪ for the action explanation strength.