This paper is an analysis of the term nu guan女冠 (woman's cap) for Taoist priestesses in regard to its gender and religious meaning. Through a comparative study of the initiation rites for young men (capping ceremony; guan li冠禮) and young women (hair-pinning ceremony, ji li 笄禮) in the Zhou dynasty, the author points out that the cap (guan冠) represented men's privileges, in which women had no part. Based on the above observation, this paper investigates the way in which Taoist traditions established a link between women and the guan冠. Detailed textual research on Taoist workds from the Six dynasties to the Tang period demonstrates that the connection was formed through the function of guan as an emblem of an official (guan官). In the hierarchical and bureaucratic would of the Shang Qing School, male and female immortals acquired the identity of heavenly officials. Various kinds of guan冠were bestowed on female as well as male immortals. Taoist priestesses also wore a guan冠according to their religious rank, and their guan冠matched the images and identities of the female immortals. At the same time, the term nu guan 女冠appeared as a formal designation for Taoist priestesses, especially in the Tang dynasty. For gender and religious studies, the most important observation is that the power of a Taoist priestess, embodied by her guan冠, which had formerly been a symbol of male privileges in traditional rites, came form the other world. This helps us gain a deeper understanding of the religious authority and identity of Taoist priestesses in medieval China.