With the input output table and its supplemental employment table, firstly this paper uses the structural decomposition analysis framework exploring the factors which cause the movements of Taiwan's labor force the period 1991-1996. Secondly, by building the social accounting matrix, this paper applies the extended input model to simulate the effects of export change on income distribution and employment. The results indicate the change of labor force allocation among industries follows the characteristics of industrial structural changes over the period. Though the technical change boosting the labor productivity has the employment-reducing effect, it is offset by the employment-increasing effect of continuing economic growth. Besides, technical change cause the substitution between occupations in the employment, specifically , the demand for professionals increasing most sharply. Export change following the past track will cause a rise in the inequality of the income distribution among the five equal divisions of households. The main reason is that the factor incomes change unevenly among different industries and the share in which the compensation of the highly skilled workers goes to the richest household division rises significantly.