While five-phases theory (metal, wood, water, fire and earth) was still a dominant theory for Chinese understanding of natural phenomena in late Ming, Jesuits transmitted western learning, including Aristotelian fourelements theory (fire, air, water and earth), for the propagation of Christian faith. In fact, the encounter of these two theory of matter reflected the confrontation between Jesuit and Neo-Confucian (sep. Zhu Xi's) worldviews. In this paper the author will take the position of Jesuits to see how did they transmit western four-elements theory in this background. At the time Jesuits and Neo-Confucians had different views on the origin of the universe, theory of matter, and the nature of human soul. In the Tienzhu shiyi 天主實義, in which Jesuit and Zhu Xi's worldviews are encountered, Matteo Ricci mentions four-elements theory and five-phases theory in the context of his proofs of the existence of the Creator and the immortality of human soul. In the Qian kun ti yi 乾坤體義, in order to establish four-elements theory, Ricci attacks Chinese five-phases theory on the one hand, however, he barrows some Chinese terms to make four-elements theory more accommodated to Chinese literati on the other hand. Later, in the Aristotelian traditions of Meteorology and On the Heavens, de Ursis, Vagnoni and Furtado respectively extends four-elements theory in Taixi shuifa 泰西水法, Kongji gezhi 空際格致 and Huan you quan 寰有詮 without forgetting to propagate Christian faith.