The purposes of this study were (1)to analysis the process of network integrated into science instruction, (2)to understand the effects of using the network technology on student's learning, (3)to investigate the potential barriers of using the network technology on students, (4)to understand students' attitudes toward the network technology, and (5)to understand students' perception on network-supported learning. The researcher conducted a case study and chose 118 5th grad students, and one science teacher of Chas-Liao Elementary School at Kaohsiung County as the research subjects. This study was a one-year research. The subjects participated into four kinds of network instruction activities that included using network technology as the resource of instructional materials, designing worksheets, writing research reports, and communication uses. This study used both quantitative and qualitative methods to collect the data. The research methods included questionnaire survey, interviews, observations, and document analysis. Based on the research results and findings, a "Network Learning Golden Triangle Model" was proposed. It suggested that the design of successful network-supported learning activities should consider four important factors including learners, hardware and software, teacher(s), and curriculum at the same time.