The liberos have been included in the completive rules since 1999. The purpose of liberos is to hope to make the games more exciting. The usages of liberos plays an important role that influences the outcome of competitions and that attracts audience. This paper hopes to measure the mental conditions of University and College Volleyball liberos before matcher by the Mental Technical Ability Scales, and to provide the result of this survey for volleyball players and coaches as the reference of their training. The samplers of this study were 12 male volleyball liberos of the University and college for the preliminary competition in 2004 , and the investigating time was before the preliminary competition. The measuring tool was originated from the Athlete Mental. Technical scales and revised for volleyball players. The results follow: (l) The performance of Male volleyball liberos of University and college for the preliminary competition in 2004 is good in "peaking under pressure and coping with adversity", "coachability", "confidence", "concentrion" and "motivation." (2) The intensity of each performance follows the descending order: "motivation" "Peaking under pressure and coping with adversity" "coach ability" "confidence" and "concentration".